Battery breakthroughs abound
Filed under: EV/Plug-in, Hybrid

In an attempt to keep our readers up to date on the very latest developments in technology as it pertains to transportation and the lessening of our carbon footprints, we often burn the midnight oil and labor to understand technical papers until our brains cramp and ears bleed. OK, maybe I'm the only one with the ear thing but what I'm trying to get across is that we are not slackers (Not that there is anything wrong with that.) And it is in that spirit of brain-crampedness (and sore ears) we present you now with some of the latest news of breakthroughs
in the batteries that may one day power your hybrid or electric car.
We all know that our modern batteries do their thing (charge and discharge) by sending lithium ions back and forth between the anode (where the current comes in) and cathode (where the current goes out). This action is what eventually degrades your electrodes (anodes and cathodes). By improving the materials that bear this beating, scientists aim to increase the amount of energy batteries hold as well as the number of times you can recharge them. Hear about a couple of these efforts after the break.
Tin is one of the materials thought to hold promise as an electrode because it theoretically should hold onto a lot of energy. Unfortunately, it breaks down easily from the passing of the lithium ions. Scientists at the Institute of Chemistry at the Chinese Academy of Sciences think they may have come up with a clever way around this by enclosing nano-sized bits of tin inside elastic hollow carbon spheres, as you can see in the photograph above. The way they accomplish this trick is a little complicated but here is a link to an article in Nanowerk that explains it all in painstaking detail. The result of all this nano-manipulation is an anode with a high specific energy capacity and good cycling performance. To top it all off the researchers believe "their results successfully demonstrate the power of the strategy of using elastic hollow carbon spheres as buffer and container and could be extended to other anode and cathode materials." Exciting stuff.
The other news comes to us from this article in Technology Review about work being carried out at the Argonne
National Laboratory. The over-achieving scientists there have made safety improvements, increased the power density and number of charge cycles lithium ion batteries with cobalt oxide electrodes can perform. Not only that, but they have already licensed the technology to a major materials supplier, Toda Kogyo of Japan. Their improvements were achieved by creating a new composite electrode with the cobalt oxide and an electrochemically inactive material. Although this should enable the battery to hold up to 30 percent more energy, the article claims that it is not able to discharge at rates high enough to make it useful for high- power applications such as hybrid and electric cars. Not yet anyway, so the work there continues.[Source: Nanowerk / Technology Review]











Reader Comments (Page 1 of 1)
4-07-2008 @ 5:27PM
KarenRei said...
And let's not downplay the energy density we're talking about here; it's similar to that of the silicon nanowire anode being developed by Yi Cui. A graphite anode typically holds 300-400Wh/kg (overall battery density is ~160Wh/kg once you add in a LiCoO2 cathode). These tin nanoparticle anodes hold 831Ah/kg, and are higher voltage than usual, so you're looking at several thousand Wh/kg. I.e., an order of magnitude higher energy density in the anode. The only downside is that it currently loses 30% capacity in 100 cycles. Even if that can't be overcome, it's still a huge breakthrough. Correction: *another* huge breakthrough.
Unfortunately, we have somewhat of a surplus on breakthroughs with anodes, and could use some more cathode breakthroughs. Come on, researchers, help us out here! :) The best I've seen so far is Argonne's hybrid Li2MnO3/LiMO2 or LiM2O4 cathode, where M is manganese or nickel. They can get over 500Wh/kg in the cathode with Li2O-stabilized alpha-MnO2. There's also Hybrid Techologies announced cathode improvement which has even higher reported energy density, but I don't put as much faith in them as I do in Argonne.
Anyways, combining either the silicon nanowire or tin nanoparticle anodes with that cathode, that'd be over 400Wh/kg for the battery as a whole -- a 3x improvement over laptop batteries and 4x improvement over lithium phosphate batteries. So, a Tesla would go >700 miles and an Aptera would go >450 miles.
As far as I can tell, at least.
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4-07-2008 @ 5:28PM
ug said...
Sorry. Cobalt isn't going to be used in EV applications. That's the volatile stuff.
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4-07-2008 @ 6:51PM
Chris M said...
Sorry, ug, but LiIon batteries using Cobalt Oxide are already being used in the Tesla Roadster, due to their high energy density, high power density, and reasonable cost.
The problem with cobalt oxide is that if it gets too hot, it breaks down and releases the oxygen, and that oxygen reacts with the hydrocarbon electrolyte and lithium, resulting in fires.
Tesla Motors developed active and passive methods to keep those batteries safe and cool, and even with the extra safety devices their Energy Storage System still gets a respectable 130 wh per Kg.
Once these newer developments are fully researched an put into mass production, which may take a few years, Tesla Motors and other EV makers will put them to good use.
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4-07-2008 @ 8:19PM
kert said...
::The problem with cobalt oxide is that if it gets too hot, it breaks down and releases the oxygen
Not to mention, Cobalt is the reason why commonly used lithium-ion batteries cant come down in price: its expensive.
Lithium phosphate doesnt contain anything that expensive.
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4-07-2008 @ 11:01PM
TG said...
Well I really appreciate the extra effort you go to, Domenick, for AutoBlogGreen.com.
One could pick a winner from these names and info you provide and make $2500 on a stock grow to a nice profit.
Too soon yet of course, but these informative posts help us get a background.
There are the two choices GM seems to be making for the volt, yet that is not solid yet either.
I imagine once a winner is selected, they will just buy them out using their own Cobasys battery outfit. OK if one owns that stock early enough.
Wiser investors could likely correct my thinking, however that seems to be how it looks from here. = TG
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4-08-2008 @ 1:30PM
Ben said...
Hmm... lithium batteries definitely have power... But with global supplies physically limited I'm thinking we'd be unwise to cite this as the only option.
(Maybe I misunderstood the article, because I don't know the specific batteries you were talking about.) The foam lead matrix should also be cited because it has far better performance than a standard lead plate battery (and very little government R&D dollars unlike lithium.)
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4-08-2008 @ 9:10PM
Kevin Nugent said...
Pretty cool . keep working at it
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